ET has a candid look at Brad Pitt and Angelina Jolie as they joined their celebrity peers at the Museum of Contemporary Art’s (MOCA) 30th Anniversary Gala in Los Angeles, Calif. on Saturday night.

The couple had some laughs as they followed their tour guide through the museum.

“It’s going to be an amazing night to look at the art,” actor Neil Patrick Harris said prior to the event. “And Lady Gaga is dancing with ballet people so that will be kind of crazy.”

Watch the video for more inside glimpses into Brad and Angie’s date night and for more artsy moments from the other stars who attended, including James Franco and Eva Mendes.

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Irish star Pierce Brosnan joined Hollywood A-listers Brad Pitt and Angelina Jolie at a private session with Lady Gaga in LA.

Brosnan, with his wife Keeley Shaye Smith, joined 1,000-plus special guests at the special party for the 30th anniversary of the Museum of Contemporary Art in Los Angeles.

Brosnan hailed Lady Gaga’s performance of her new ballad, “Speechless,” which was part of a production masterminded by Italian artist Francesco Vezzoli and also included a performance from Russia’s famed Bolshoi Ballet.

The event raised nearly $4 million for MOCA — greatly helped by the sale of GaGa’s pink piano, which was designed by Internationally renowned English artist Damien Steven Hirst, one of the the most prominent members of the group known as “Young British Artists” who dominated the art scene in England during the 1990s. He is considered to be the world’s richest living artist.

The piano went for $450,000.

After the event, the Hollywood elite – including Gwen Stefani, Gavin Rossdale, Marisa Tomei, Guy Richie – joined Tom Ford and Nicky Hilton for the after party hosted by Prism Gallery, Dasha Zhukova and Pop magazine.

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No bunnies for Angelina Jolie and Brad Pitt. When they agreed to design a limited-edition jewelry and baby collection for high-end international jeweler Asprey, they settled on a slightly more sinister motif: snakes.

Their jewelry line, in stores (including one on Madison Avenue) this week, includes a silver baby spoon, an eggcup, tooth box, as well as micropave diamond-encrusted pendants and rings, emblazoned with or shaped like a curving serpent, Women’s Wear Daily reports. Jolie latched on to the snake when she was given a ring while pregnant with her third child, Shiloh, and considers it a protective emblem.

Proceeds from “Protector” collection will go to one of Jolie’s charities, Education Partnership for Children of Conflict, which raises money to school child victims of war, conflict and natural disasters.

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Brad and Angelina attending the MOCA NEW 30th Anniversary Gala. I just added some photos from it. Most are MQ, but I did add in a couple HQ one’s. Enjoy!

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Public Appearances > Events from 2009 > MOCA NEW 30th Anniversary Gala

I just added a couple HQ photos of Brad attending the Tokyo premiere of his movie Inglorious Basterds. Enjoy!

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Public Appearances > Events from 2009 > “Inglorious Basterds” Tokyo Premiere

Brad Pitt is heading to a different interest as he has taken up a new hobby in a bid to get some time alone from partner Angelina Jolie.

The “Inglorious Basterds” actor, who raises six kids with “Changeling” actress, has reportedly enrolled in wine-making classes. A source claimed that the actor loves learning how the wine is made.

Meanwhile, Angelina was believed to be adopt another kid without Brad because she is determined to complete her rainbow family. A spokesman for the Immigration and Naturalization Service in Washington D.C. confirmed that her name was on the adoption papers.

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Angelina Jolie and Brad Pitt are planning on adopt baby number seven! Because nothing fixes a tense relationship like yet another child, the pair are currently investigating the possibility of adopting a girl from Syria.

However Brad (who’s maybe more sensible than we thought) won’t be named on the adoption papers, with a soirve telling OK! Magazine that ‘(Brad) has made it clear that six children are more than he can handle. The idea of one more seemed ludicrous, but Angie is determined to complete her rainbow family.’??

Looks like we can expect Brad to purchase another mid-life crisis motorbike sometime soon.

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The new Us Weekly (on newsstands now) has the exclusive first look at what’s really inside a shocking new tell-all about Brad Pitt and Angelina Jolie — and reveals the truth behind some of the alleged bombshells.

Brangelina: The Untold Story of Brad Pitt and Angelina Jolie reports that “they’ve broken up so many times it would make your head spin.”

It also claims Jolie “has a temper like a cobra.” The book even alleges that she confessed to hiring a hit man to kill her in 1998 because she was so distraught.

See why Angelina Jolie made Us’ grossest kisses slideshow

Us Weekly reports that the actress, 34, still has her battles with Pitt, 45 – especially when it comes to their six children.

See Brad and Angelina’s biggest PDA moments overseas

“They fight all the time about the kids – where to put toys, saying the wrong thing to a nanny, not cleaning up,” one source tells Us Weekly. “Like cats and dogs.”

See photos of Brad Pitt and other stars involved in stripper scandals

For more on Jolie and Pitt – including the truth behind Pitt’s “secret meetings” with Jennifer Aniston, why the tell-all claims Pitt and Jolie will split by “Christmas 2010″ and inside Jolie’s decision to reconcile with her father after an eight-year rift – pick up the new issue of Us Weekly today!

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Brad Pitt is on the White House guest list.

The star is one of several celebs who have visited the White House since President Barack Obama took office, according to White House records released on Friday.

In fact, Brad has made the trip twice.

Oprah Winfrey, a major backer of Obama during his presidential campaign, has also made a pair of appearances at the White House.

Other celebs who have made the trip include George Clooney, Denzel Washington, director Michael Moore and tennis star Serena Williams.

The White House’s most popular celeb, though, might be basketball legend Michael Jordan, whose name is listed eight times (as both “Mike” and “Michael”) – enough to wonder if the NBA great has gone one-on-one with the basketball-loving president.

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After Brad Pitt bumped into another vehicle while riding one of his motorcycles in LA on Oct. 24, the star’s biggest concern wasn’t the damaged bike or the scratches on the other car — it was how angry his partner, Angelina Jolie, would be when she found out about the accident.

After the incident, Brad sought refuge in a nearby apartment complex. “He told the building manager that Angie was going to kill him because she thinks motorcycles are too dangerous,” building resident Talia Schwartz reveals to Life & Style.

The mishap occurred when Brad tried to squeeze his custom-made bike between two cars that were stopped in traffic. “He misjudged the space between the cars, and it was just a hair too small to fit his bike,” an eyewitness tells Life & Style.

For more on Brad’s crash, pick up the latest issue of Life & Style, on newsstands now!

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I just added some HQ photos of Brad visiting Iraqi refugees in Syria earlier this month. I want to thank Sheeda over at Johnny Depp Network for these! I really appreciate it! Enjoy!

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Candids > Candids from 2009 > 10-02 – Brad Visits Iraqi Refugees In Syria

When Brad Pitt dumped his badass new bike in Hollywood traffic on Saturday, it went down not with a bang but a whimper. After all, an accident that occurs when a vehicle is barely moving is bound to be inglourious at best.

TMZ reports that Pitt was trying to negotiate between a car stopped at a light (on his left) and a parked car on his right, when his handlebars clipped the parked car. He lost control of the bike and it skidded out from under him (see video).

He wasn’t injured, nor did he seem upset. Charming as ever, he stood around and shot the breeze with fans while he waited for his bike to be towed, according to a Radar Online report..

The next day he was seen sporting a new Camaro. (His dedication to skin care products obviously doesn’t stop him from being a manly man.)

Here’s the accident video:

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Brad Pitt didn’t escape completely unscathed from his minor motorcycle accident in Los Angeles over the weekend.

The dad of six, 45, showed off a few scratches while running errands in L.A. Monday afternoon.

Pitt was reportedly cut off by a paparazzi photographer when he fell off his bike. He was not seriously hurt, and was caught on camera saying “I’m fine!” after getting up.

For his Monday outing, he traded his two wheels for brand new Chevy Camaro.

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December 1st is a big day for Angelina Jolie and Brad Pitt. It is the first day that copies of Brangelina Exposed come out.

Ian Halperin is the writer, who is also an investigative journalist and the number one seller of Unmasked: The Final Years of Michael Jackson.

rangelina Exposed will answer questions of how the couple has “successfully manipulated the public into believing a glamorous fairytale that bears little resemblance to the reality of the pair’s life together,” says a press release.

Halperin also speaks about Pitt’s marriage to Jennifer Aniston and the “real reason” for their split.

The writer also spills about Jolie’s past with “new details of her volatile relationship with and estrangement from her father Jon Voight, her struggles with suicidal impulses, her heroin use, her sexual exploit and her remarkable rise to become an Oscar-winning actress.”

Halperin will tell about “the key figure behind the scenes who orchestrated her makeover into a United Nations Goodwill Ambassador.”

But the book also points fingers, saying that not all is well.

“Jolie’s personal lifestyle choices are not only affecting her growing family,” the release says, “but causing serious and potentially irreparable tensions with Pitt.”

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HOLLYWOOD super-couple Brad Pitt and Angelina Jolie have come to blows yet again — because he wants the actress to put their family before her career.

Brad is said to be furious that Angelina backtracked on her promise to take some time off to look after the couple’s six kids and has gone back to work.

“She says she wants to put her family first — but when a good role comes along, she forgets all that. Brad thinks she’s being selfish,” a source told In Touch Weekly magazine.

“Angelina is throwing herself into work as a way not to dwell on her crumbling relationship with Brad.

“Pretending to be someone else for 14 hours a day makes her problems feel less real.”

It was recently claimed that Pitt and Jolie are struggling to control Maddox, 8; Pax, 5; Zahara, 4; Shiloh, 3; and 15-month-old twins Knox and Vivienne

“They have dinner around 11 p.m. And it’s a real smorgasbord of snacks — cheese and crackers, chips, grapes and chocolate,” a source said earlier this month.

“They all sleep in Brad and Angie’s bed. And the kids wear whatever they want. Sometimes Zahara falls asleep in her Sleeping Beauty dress, which has permanent chocolate milk stains on it.

“Maddox and Pax are double trouble. They have every sort of toy known to man, including paint guns, which they splatter all over the walls of the house.

“Maddox tends to get special treatment. It was his idea to pierce Vivienne’s ears. After he said he wanted to do it himself with a pin, Angie decided to have it done professionally.

“Brad is starting to get tougher… he does tell them ‘no’ and holds them accountable for their actions. The trouble is they just run to Mom, and she caves. She doesn’t want her kids to have that kind of life… she gives them their freedom because she wants their ‘souls to evolve.’”

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